Liverpool are unbeaten in the Premier League after five games this season, but so are PSG - and Klopp's defence will be put to the test against the likes of Neymar and Kylian Mbappe from the very first game in Group C.
Scroll down for Standard Sport's preview...
TV, online and live stream coverage
Standard Sport will have LIVE coverage from Anfield on the night, with Liverpool correspondent David Lynch in attendance.
Click here for Liverpool's official ticket website.
Betting tips via Betfair | UK users only | Subject to change
- Liverpool to win 4-3: 66/1
- PSG to win 2-1: 10/1
- Salah to score: 10/11
- Neymar to score last: 4/1
- Mbappe to score first: 11/2
Click here to find the latest match odds and place a bet
Head to head record
The two sides have only faced each other twice before in an official competition.
Liverpool won the first leg of the 1997 Uefa Cup Winners' Cup semi-final 2-0, but PSG went through with a 3-0 second-leg win before being beaten in the final by Barcelona.
Roberto Firmino may miss out for Liverpool after suffering an eye injury against Tottenham following a sickening clash with Jan Vertonghen in which the Spurs defender's finger accidentally lodged in the forward's eye socket.
Firmino had "an abrasion of the eye, but there will be no lasting damage" after he was assessed at a London hospital.
As for PSG, Neymar and Mbappe will return after being rested in the French champions' 4-0 win against St Etienne.